Web(TMEDA) in the presence of O 2 as solubilising ligand for copper (I) halides8 (scheme 3). The catalytic version of Glaser coupling using copper-TMEDA complex under air is termed as the Hay Coupling reaction or Glaser-Hay coupling. R H R R CuCl/TMEDA O 2, solvent 2 50 Scheme 3 Glaser-Hay coupling reaction The copper-TMEDA complex is soluble in a ... WebNov 27, 2006 · Typical procedure of macrocycle 1a: A solution of 6a (1.75 g, 3.07 mmol) and CuCl (OH)–TMEDA (68.5 mg, 0.30 mmol) in CHCl 3 (500 ml) was stirred for one day at room temperature under air. The reaction mixture was washed with water (× …

Synthesis of regiocontrolled triarylamine-based polymer …

WebOxidation of the phenols in presence of [CuCl(OH)(TMEDA)]2 Para-para coupling QuinoneBisphenol Diphenoquinone Oxidative para-para coupling of phenols para-para coupling Oxidation conditions Phenol / Cu (100 / 8) Room temperature 21 °C EtOH 96 h. Oxidation of phenol in the presence of CuCl(OH)(TMEDA) Reagent Yield(%)Quinone … WebCuCl(OH)TMEDA (0.952g, 2.05mmol, 2.5mol% to the monomer) and TMEDA (4.75g, 40.9mmol) were added in this order. The flask was purged with oxygen donate blood with prostate medication

Aerobic Copper Catalytic Oxidation of Methylene and

WebMar 8, 2006 · The copolymerization with the CuCl(OH)-TMEDA catalyst afforded poly-(1/2) as the methanol-ethyl acetate-1 N HCl (1/3/0.2, v/v/v)-insoluble fraction in 40% yield with a number average molecular weight (M n) of 6.9×10 3, and the unit ratio in the copolymer was estimated from the 1 H NMR analysis of the acetylated poly-(1/2) to be 1:2=56:44 ... WebOxidative Coupling Polymerization of Silicon-Tethered p-Alkoxyphenol Derivatives with CuCl(OH)-N,N,N′,N′-Tetramethylethylenediamine Catalyst August 2005 Polymer Journal … donate boat to pbs